Efecto del sistema de vulcanización en la red entrecruzada y en la reacción química de vulcanización del caucho natural

Se presenta una revisión sobre el efecto del sistema de vulcanización en la estructura formada durante la reacción de vulcanización, en la cinética de la reacción y en las propiedades de formulaciones que emplean caucho natural. Se encontró que aún existen aspectos por investigar dada la variedad de acelerantes, proporciones acelerante/azufre, tipos de caucho natural y formulaciones que emplean caucho natural. La mayor parte de la literatura evalúa la reacción de vulcanización mediante reometría de vulcanización y calorimetría diferencial de barrido (DSC), pero estas técnicas no permiten identificar el tipo de enlaces sulfídicos formados ni la densidad de enlaces entrecruzados. La temática es de gran interés científico e industrial pues el... Ver más

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spelling Efecto del sistema de vulcanización en la red entrecruzada y en la reacción química de vulcanización del caucho natural
Mark, J.E., Erman, B., Roland, M., 2013. The science and technology of rubber (4th ed.). Acad. Press.
Morrison, N.J., Porter, M., 1984a. Temperature effects on the stability of intermediates and crosslinks in sulfur vulcanization. Rubber Chem. Technol. 57, 63–85.
Morrison, N.J., 1984b. The formation of crosslink precursors in the sulfur vulcanization of natural rubber. Rubber Chem. Technol. 57, 97–103.
Morrison, N.J., 1984a. The reactions of crosslink precursors in natural rubber. Rubber Chem. Technol. 57, 86–96.
Mayer, R., 1977. Organic Chemistry of sulfur, S. OAE. ed. Plenum Press, New York.
Marzocca, A.J., Steren, C.A., Raimondo, R.B., Cerveny, S., 2004. Influence of the cure level on the monomeric friction coefficient of natural rubber vulcanizates. Polym. Int. 53, 646–655. http://doi.wiley.com/10.1002/pi.1378. doi:10.1002/pi.1378
Marzocca, A.J., Rodriguez Garraza, A.L., Sorichetti, P., Mosca, H.O., 2010. Cure kinetics and swelling behaviour in polybutadiene rubber. Polym. Test. 29, 477–482. http://linkinghub.elsevier.com/retrieve/pii/S0142941810000280. doi:10.1016/j.polymertesting.2010.02.008
Marzocca, A.J., Cerveny, S., Raimondo, R.B., 1997. Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model. J. Appl. Polym. Sci. 66, 1085–1092. http://dipc.ehu.es/cerveny/index_htm_files/journal%20of%20polym%20sci%2066%20(1997)%201085.pdf.
Marzocca, A.J., 2003. Relación entre la cinetica de formación de entrecruzamientos y las propiedades mecánicas de elastomeros vulcanizados. Presented at the Jornadas SAM/CONAMET/Simposio materia, pp. 886–889.
Marzocca, A.J., 2007. Evaluation of the polymer–solvent interaction parameter χ for the system cured styrene butadiene rubber and toluene. Eur. Polym. J. 43, 2682–2689. http://linkinghub.elsevier.com/retrieve/pii/S0014305707001358. doi:10.1016/j.eurpolymj.2007.02.034
Martinez Valdés, M., 2012. Financiamiento, insumo para las empresas productoras de hule natural: procedimientos, riesgos y requisitos para una dispersión de recursos financieros eficiente. Editor. Académica Esp.
Mansilla, M.A., Quasso, F., Marzocca, A.J., 2007. CARACTERIZACIÓN DE MEZCLAS VULCANIZADAS DE CAUCHO ESTIRENO BUTADIENO Y CAUCHO NATURAL http://www.materiales-org.ar/sitio/biblioteca/CONAMET-SAM2007/sam%20conamet%2007/pdf/T%C3%B3pico%2010%20-%20Materiales%20Polim%C3%A9ricos/10-14%20MansillaM%20(O).pdf.
Mukhopadhyay, R., Bhowmick, A.K., De, S.K., 1978. Effect of vulcanzation temperature and synergism of accelerators on the network and technical properties of efficiently vulcanized natural rubber mixes. Polymer 19, 1176–1180.
Mansilla, M.A., 2012. Influencia de la microestructura en las propiedades mecánicas y térmicas de mezclas de caucho natural y caucho estireno butadieno http://digital.bl.fcen.uba.ar/Download/Tesis/Tesis_5117_Mansilla.pdf.
Loo, C.T., 1974. High temperature vulcanization of elastomers: 3. Network structure of efficiently vulcanized natural rubber mixes. Polymer 15, 729–737.
Lloyd, D.G., 1991. Additives in rubber processing. Mater. Des. 12, 139–146. http://www.sciencedirect.com/science/article/pii/026130699190122K.
Kuptsov, A.H., Zhizhin, G.N., 1998. Handbook of fourier transform Raman and Infrared spectra of polymers, Elsevier. ed.
Krishnan, S., 2015. Natural rubber latex filler masterbatch: preparation, processing and evaluation. Sch. Press.
Kamal, M.R., Sourour, S., 1973. Kinetics and thermal characterization of thermoset cure. Polym. Eng. Sci. 13, 59–64.
Jarny, Y., 2000. SIMULTANEOUS ESTIMATION OF KINETIC PARAMETERS USING GENETIC ALGORITHMS, in: Inverse Problems in Engineering: Theory and Practice: Presented at the 3rd International Conference on Inverse Problems in Engineering, Theory and Practice, June 13-18, 1999, Port Ludlow, Washington. p. 263. http://www.me.ua.edu/3icipe/papers/paper61.pdf.
Heinrich, G., Straube, E., Helmis, G., 1988. Rubber elasticity of polymer networks: Theories. Adv. Polym. Sci. 85, 33–87.
Heideman, G., Datta, R.N., Noordermeer, J.W.M., Baarle, B.V., 2004. Activators in accelerated sulfur vulcanization. Rubber Chem. Technol. 77, 512–541.
Heideman, G., 2004. Reduced zinc oxide levels in sulphur vulcanisation of rubber compounds: mechanistic aspects of the role of activators and multifunctional additives. s.n.], S.l.
Hauser, E.A., Sze, M.C., 1942. Chemical reactions during vulcanization III. J. Phys. Chem. 46, 118–131.
Morrison, N.J., Porter, M., 1984b. Crosslinking of rubbers. Synth. Charact. React. Appl. Polym. G Allen Ed Pergamon Press 57, 115.
Mukhopadhyay, R., De, S.K., 1977. Effect of vulcanization temperature and vulcanization systems on the structure and properties of natural rubber vulcanizates. Polymer 18, 1243–1249.
Gradwell, M.H.S., Merwe, M.J., 1999a. Reaction of 2-t-butilbenzothiazole sulfenamida with sulfur and zinc oxide in the absence of rubber. Rubber Chem. Technol. 72, 55–64.
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Urrego, W., Giraldo, D., Álvarez-Láinez, M., 2012. Análisis cuantitativo por FTIR y evaluación comparativa de la descomposición térmica de tres variedades de caucho natural Colombiano. Presented at the SLAP 2012 XIII Simposio latinoamericano de polímeros, Colombia.
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Revista EIA
Fondo Editorial EIA - Universidad EIA
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Artículo de revista
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14
Elastómeros
Polímeros
Ciencia de los Materiales
agente vulcanizante
https://creativecommons.org/licenses/by-nc-sa/4.0/
red entrecruzada
reacción de vulcanización
sistema de vulcanización
Caucho natural
Posada Correa, Juan Carlos
Giraldo Vásquez, Diego Hernán
Velásquez Restrepo, Sandra Milena
Urrego Yepes, William
Se presenta una revisión sobre el efecto del sistema de vulcanización en la estructura formada durante la reacción de vulcanización, en la cinética de la reacción y en las propiedades de formulaciones que emplean caucho natural. Se encontró que aún existen aspectos por investigar dada la variedad de acelerantes, proporciones acelerante/azufre, tipos de caucho natural y formulaciones que emplean caucho natural. La mayor parte de la literatura evalúa la reacción de vulcanización mediante reometría de vulcanización y calorimetría diferencial de barrido (DSC), pero estas técnicas no permiten identificar el tipo de enlaces sulfídicos formados ni la densidad de enlaces entrecruzados. La temática es de gran interés científico e industrial pues el caucho natural es el caucho más comercializado a nivel mundial, y su vulcanización se realiza en la gran mayoría de las formulaciones empleando azufre como agente entrecruzante.
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https://revistas.eia.edu.co/index.php/reveia/article/view/1144
Revista EIA - 2018
ASTM D5289, 2012. Test Method for Rubber Property--Vulcanization Using Rotorless Cure Meters. ASTM International.
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Publication
Allen, P.W., Bristow, G.M., 1963. The gel phase in Natural Rubber. J. Appl. Polym. Sci. 7, 603–615.
Akay M., 2012. Introduction To Polymer Sciense And Technology. 1 St Ed. Mustafa Akay Ventus Publ. ApS.
Akiba, M., Hashim, A.S., 1997. Vulcanization and crosslinking in elastomers. Prog. Polym. Sci. 22, 475–521.
Akinlabi, A.K., Okieimen, F.E., Egharevba, F., Malomo, D., 2006. Investigation of the effect of mixing schemes on rheological and physico-mechanical properties of modified natural rubber blends. Mater. Des. 27, 783–788. doi:10.1016/j.matdes.2005.01.007
Journal article
Efecto del sistema de vulcanización en la red entrecruzada y en la reacción química de vulcanización del caucho natural
2017-11-02 00:00:00
2017-11-02 00:00:00
https://revistas.eia.edu.co/index.php/reveia/article/download/1144/1166
2017-11-02
115
1794-1237
2463-0950
10.24050/reia.v14i28.1144
https://doi.org/10.24050/reia.v14i28.1144
99
institution UNIVERSIDAD EIA
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country_str Colombia
collection Revista EIA
title Efecto del sistema de vulcanización en la red entrecruzada y en la reacción química de vulcanización del caucho natural
spellingShingle Efecto del sistema de vulcanización en la red entrecruzada y en la reacción química de vulcanización del caucho natural
Posada Correa, Juan Carlos
Giraldo Vásquez, Diego Hernán
Velásquez Restrepo, Sandra Milena
Urrego Yepes, William
acelerantes
Elastómeros
Polímeros
Ciencia de los Materiales
agente vulcanizante
red entrecruzada
reacción de vulcanización
sistema de vulcanización
Caucho natural
title_short Efecto del sistema de vulcanización en la red entrecruzada y en la reacción química de vulcanización del caucho natural
title_full Efecto del sistema de vulcanización en la red entrecruzada y en la reacción química de vulcanización del caucho natural
title_fullStr Efecto del sistema de vulcanización en la red entrecruzada y en la reacción química de vulcanización del caucho natural
title_full_unstemmed Efecto del sistema de vulcanización en la red entrecruzada y en la reacción química de vulcanización del caucho natural
title_sort efecto del sistema de vulcanización en la red entrecruzada y en la reacción química de vulcanización del caucho natural
title_eng Efecto del sistema de vulcanización en la red entrecruzada y en la reacción química de vulcanización del caucho natural
description Se presenta una revisión sobre el efecto del sistema de vulcanización en la estructura formada durante la reacción de vulcanización, en la cinética de la reacción y en las propiedades de formulaciones que emplean caucho natural. Se encontró que aún existen aspectos por investigar dada la variedad de acelerantes, proporciones acelerante/azufre, tipos de caucho natural y formulaciones que emplean caucho natural. La mayor parte de la literatura evalúa la reacción de vulcanización mediante reometría de vulcanización y calorimetría diferencial de barrido (DSC), pero estas técnicas no permiten identificar el tipo de enlaces sulfídicos formados ni la densidad de enlaces entrecruzados. La temática es de gran interés científico e industrial pues el caucho natural es el caucho más comercializado a nivel mundial, y su vulcanización se realiza en la gran mayoría de las formulaciones empleando azufre como agente entrecruzante.
author Posada Correa, Juan Carlos
Giraldo Vásquez, Diego Hernán
Velásquez Restrepo, Sandra Milena
Urrego Yepes, William
author_facet Posada Correa, Juan Carlos
Giraldo Vásquez, Diego Hernán
Velásquez Restrepo, Sandra Milena
Urrego Yepes, William
topicspa_str_mv acelerantes
Elastómeros
Polímeros
Ciencia de los Materiales
agente vulcanizante
red entrecruzada
reacción de vulcanización
sistema de vulcanización
Caucho natural
topic acelerantes
Elastómeros
Polímeros
Ciencia de los Materiales
agente vulcanizante
red entrecruzada
reacción de vulcanización
sistema de vulcanización
Caucho natural
topic_facet acelerantes
Elastómeros
Polímeros
Ciencia de los Materiales
agente vulcanizante
red entrecruzada
reacción de vulcanización
sistema de vulcanización
Caucho natural
citationvolume 14
citationissue 28
publisher Fondo Editorial EIA - Universidad EIA
ispartofjournal Revista EIA
source https://revistas.eia.edu.co/index.php/reveia/article/view/1144
language Español
format Article
rights http://purl.org/coar/access_right/c_abf2
info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/4.0/
Revista EIA - 2018
references Mark, J.E., Erman, B., Roland, M., 2013. The science and technology of rubber (4th ed.). Acad. Press.
Morrison, N.J., Porter, M., 1984a. Temperature effects on the stability of intermediates and crosslinks in sulfur vulcanization. Rubber Chem. Technol. 57, 63–85.
Morrison, N.J., 1984b. The formation of crosslink precursors in the sulfur vulcanization of natural rubber. Rubber Chem. Technol. 57, 97–103.
Morrison, N.J., 1984a. The reactions of crosslink precursors in natural rubber. Rubber Chem. Technol. 57, 86–96.
Mayer, R., 1977. Organic Chemistry of sulfur, S. OAE. ed. Plenum Press, New York.
Marzocca, A.J., Steren, C.A., Raimondo, R.B., Cerveny, S., 2004. Influence of the cure level on the monomeric friction coefficient of natural rubber vulcanizates. Polym. Int. 53, 646–655. http://doi.wiley.com/10.1002/pi.1378. doi:10.1002/pi.1378
Marzocca, A.J., Rodriguez Garraza, A.L., Sorichetti, P., Mosca, H.O., 2010. Cure kinetics and swelling behaviour in polybutadiene rubber. Polym. Test. 29, 477–482. http://linkinghub.elsevier.com/retrieve/pii/S0142941810000280. doi:10.1016/j.polymertesting.2010.02.008
Marzocca, A.J., Cerveny, S., Raimondo, R.B., 1997. Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model. J. Appl. Polym. Sci. 66, 1085–1092. http://dipc.ehu.es/cerveny/index_htm_files/journal%20of%20polym%20sci%2066%20(1997)%201085.pdf.
Marzocca, A.J., 2003. Relación entre la cinetica de formación de entrecruzamientos y las propiedades mecánicas de elastomeros vulcanizados. Presented at the Jornadas SAM/CONAMET/Simposio materia, pp. 886–889.
Marzocca, A.J., 2007. Evaluation of the polymer–solvent interaction parameter χ for the system cured styrene butadiene rubber and toluene. Eur. Polym. J. 43, 2682–2689. http://linkinghub.elsevier.com/retrieve/pii/S0014305707001358. doi:10.1016/j.eurpolymj.2007.02.034
Martinez Valdés, M., 2012. Financiamiento, insumo para las empresas productoras de hule natural: procedimientos, riesgos y requisitos para una dispersión de recursos financieros eficiente. Editor. Académica Esp.
Mansilla, M.A., Quasso, F., Marzocca, A.J., 2007. CARACTERIZACIÓN DE MEZCLAS VULCANIZADAS DE CAUCHO ESTIRENO BUTADIENO Y CAUCHO NATURAL http://www.materiales-org.ar/sitio/biblioteca/CONAMET-SAM2007/sam%20conamet%2007/pdf/T%C3%B3pico%2010%20-%20Materiales%20Polim%C3%A9ricos/10-14%20MansillaM%20(O).pdf.
Mukhopadhyay, R., Bhowmick, A.K., De, S.K., 1978. Effect of vulcanzation temperature and synergism of accelerators on the network and technical properties of efficiently vulcanized natural rubber mixes. Polymer 19, 1176–1180.
Mansilla, M.A., 2012. Influencia de la microestructura en las propiedades mecánicas y térmicas de mezclas de caucho natural y caucho estireno butadieno http://digital.bl.fcen.uba.ar/Download/Tesis/Tesis_5117_Mansilla.pdf.
Loo, C.T., 1974. High temperature vulcanization of elastomers: 3. Network structure of efficiently vulcanized natural rubber mixes. Polymer 15, 729–737.
Lloyd, D.G., 1991. Additives in rubber processing. Mater. Des. 12, 139–146. http://www.sciencedirect.com/science/article/pii/026130699190122K.
Kuptsov, A.H., Zhizhin, G.N., 1998. Handbook of fourier transform Raman and Infrared spectra of polymers, Elsevier. ed.
Krishnan, S., 2015. Natural rubber latex filler masterbatch: preparation, processing and evaluation. Sch. Press.
Kamal, M.R., Sourour, S., 1973. Kinetics and thermal characterization of thermoset cure. Polym. Eng. Sci. 13, 59–64.
Jarny, Y., 2000. SIMULTANEOUS ESTIMATION OF KINETIC PARAMETERS USING GENETIC ALGORITHMS, in: Inverse Problems in Engineering: Theory and Practice: Presented at the 3rd International Conference on Inverse Problems in Engineering, Theory and Practice, June 13-18, 1999, Port Ludlow, Washington. p. 263. http://www.me.ua.edu/3icipe/papers/paper61.pdf.
Heinrich, G., Straube, E., Helmis, G., 1988. Rubber elasticity of polymer networks: Theories. Adv. Polym. Sci. 85, 33–87.
Heideman, G., Datta, R.N., Noordermeer, J.W.M., Baarle, B.V., 2004. Activators in accelerated sulfur vulcanization. Rubber Chem. Technol. 77, 512–541.
Heideman, G., 2004. Reduced zinc oxide levels in sulphur vulcanisation of rubber compounds: mechanistic aspects of the role of activators and multifunctional additives. s.n.], S.l.
Hauser, E.A., Sze, M.C., 1942. Chemical reactions during vulcanization III. J. Phys. Chem. 46, 118–131.
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